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Why does a reaction speed up at higher temperature

In Chapters 1 and 2, we met the idea that the simplest way to increase the energy of a chemical, material or body is to raise its temperature. So heating a reaction mixture gives more energy to its molecules. Although only a tiny proportion of these molecules will ever have sufficient energy to collide successfully and form an activated complex TS, even a small increase in the amounts of energy possessed by a molecule will increase the proportion that [Pg.411]

The simplest way to increase the energy of a chemical, material or body is to raise its temperature - see p. 34. [Pg.411]

By increasing the temperature T, we have not changed the magnitude of the activation energy, nor have we changed the value of AH of reaction. The increased rate is a kinetic result we have enhanced the number of successful reaction collisions per unit time. [Pg.412]

The simplest relationship between temperature T and rate constant k is given by the Arrhenius equation (Equation (8.54)), which relates the rate constant of reaction k with the thermodynamic temperature T at which the reaction is performed  [Pg.412]

Heating a reaction mixture increases the number of successful collisions between the reactant species, increasing the amount of product formed per unit time. [Pg.412]


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