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Why do we need solvation thermodynamics

Consider a general chemical reaction in the gaseous phase, written symbolically as [Pg.194]

the chemical potential of each species is written as [Pg.194]

As a simple example, suppose two monomers (M) form a dimer (D). The reaction is [Pg.195]

The equilibrium constant, and the corresponding standard Gibbs energy of this reaction, are [Pg.195]

Gibbs energy in the liquid phase, we have to transfer each of the species from the ideal-gas phase into the liquid. This transfer involves the solvation Gibbs energies of all the species participating in the reaction. [Pg.196]


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Solvation thermodynamics

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