Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Wharton oxygen transposition reaction

Reduction of a,(3-epoxy ketones by hydrazine to allylic alcohols. [Pg.616]

Synthetic utility of the Wharton reaction in alkaloids can be exemplified by the oxygen transposition of epoxyketone 28 to allylic alcohol 29.14 Many similar cases have been reported.15 16... [Pg.156]

Advantage was taken of the Wharton reaction to carry out an oxygen transposition of 32 to provide 33, which was only two steps away from 11-deoxy-prostaglandin Fi0 after de-silylation and hydrolysis.18... [Pg.157]

See other pages where Wharton oxygen transposition reaction is mentioned: [Pg.616] [Pg.432] [Pg.391] [Pg.616] [Pg.432] [Pg.391] [Pg.341] [Pg.927]

See also in sourсe #XX -- [ Pg.616 ]

See also in sourсe #XX -- [ Pg.391 ]

SEARCH

1,3-Oxygen transposition

Transposition

Transposition reactions

Wharton reaction