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Wharton oxygen transposition

Synthetic utility of the Wharton reaction in alkaloids can be exemplified by the oxygen transposition of epoxyketone 28 to allylic alcohol 29.14 Many similar cases have been reported.15 16... [Pg.156]

Advantage was taken of the Wharton reaction to carry out an oxygen transposition of 32 to provide 33, which was only two steps away from 11-deoxy-prostaglandin Fi0 after de-silylation and hydrolysis.18... [Pg.157]

See other pages where Wharton oxygen transposition is mentioned: [Pg.616]    [Pg.432]    [Pg.391]    [Pg.616]    [Pg.432]    [Pg.391]    [Pg.837]    [Pg.837]    [Pg.341]    [Pg.927]   


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1,3-Oxygen transposition

Transposition

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