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Water Molecule Rearrangement in Solvation Shell Assembly

Water Molecule Rearrangement in Solvation Shell Assembly [Pg.269]

The driving force for rearrangement of water molecules before instantaneous FC proton-electron charge transfer presents a problem. A five-molecule water superdipole assembly might acquire +25.9kT of thermal energy, but there will be a low probability that its subsequent rearrangement will direct it towards that for an intermediate state for FC electron transfer and proton discharge. This is not necessarily true for [Pg.269]



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In assembly

Molecules assemblies

Solvate shell

Solvated water molecules

Solvation in water

Solvation shell

Solvation shell assembly

Solvation shell rearrangement

Solvation water

Water molecule

Water molecule molecules

Water rearrangements

Water solvation shell

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