Water column and sediment pore-waters

It is clear from previous comments that radionuclide speciation studies must consider not only oxidation states and specific inorganic forms but also complex species arising through association with natural organic matter and the possibility of different physical states. The relative importance of these various physicochemical forms will, in practice, be dictated by a combination of the basic elemental characteristics of the radionuclide and the type of environment into which it is placed. Thus in seawater, colloidal organic complex species are likely to be far less dominant than for the same radionuclide in a very low ionic strength freshwater. In the case of soil and sediment interstitial waters or groundwaters, 

Especially interesting in a discussion of radionuclide speciation is the behaviour of the transuranium elements neptunium, plutonium, americium and curium. These form part of the actinide series of elements which resemble the lanthanides in that electrons are progressively added to the 5f instead of the 4f orbital electron shell. The effective shielding of these 5f electrons is less than for the 4f electrons of the lanthanides and the differences in energy between adjacent shells is also smaller, with the result that the actinide elements tend to display more complex chemical properties than the lanthanides, especially in relation to their oxidation-reduction behaviour (Bagnall, 1972). The effect is especially noticeable in the case of uranium, neptunium and plutonium, the last of which has the unique feature that four oxidation states Pum, Pu, Puv and Pu are 

We must also consider the situation for certain important radionuclides from a variety of different groups in the Periodic Table which are able to exist in the environment as negatively charged oxygenated species as well as various positively charged species. Important illustrations of this type are TcOf, I-and IO3. 

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