Voltammograms stripping

Potential-excitation signal and voltammogram for anodic stripping voltammetry at a hanging mercury drop electrode. 

The current during the stripping step is monitored as a function of potential, giving rise to peak-shaped voltammograms similar to that shown in Figure 11.37. The peak current is proportional to the analyte s concentration in the solution. 

In view of the limitations referred to above, and particularly the influence of electrode characteristics upon the peaks in the voltammogram, some care must be exercised in setting up an apparatus for stripping voltammetry. The optimum conditions require ... 

Voltaic cells 64. 504 Voltammetry 7, 591 anodic stripping, 621 concentration step, 621 mercury drop electrode, 623 mercury film electrode, 623 peak breadth, 622 peak current, 622 peak potential, 622 purity of reagents, 624 voltammogram, 622 D. of lead in tap water, 625 Volume distribution coefficient 196 Volume of 1 g of water at various temperatures, (T) 87... 

FIGURE 3-14 Stripping voltammograms for 2 x 10 7 M Cu2+, Pb2+, In3+ and Cd2+ at the mercury film (A) and hanging mercury drop (B) electrodes. (Reproduced with permission from reference 21.)... 

FIGURE 3-18 Stripping voltammograms for trace iodide in seawater. (Reproduced with permission from reference 39.)... 

Example 3-1 Voltammogram (a) was obtained for adsorptive stripping measurements of Fe(III) in sea water. Voltammograms (b) and (c) show successive standard additions of 4 ppb Fe(III). Find the concentration of Fe(III) in the sample. 

Fig, 16. Anodic stripping voltammogram for at the hanging mercury drop electrode. (Reprinted with permission from W. R. Heineman, in Water Quality Measurement The Modem Analytical Techniques , (H. B. Mark, Jr. and J. S. Mattson, eds.) Marcel Dekker New York, 1981)... 

Lopez-Cudero A, Cuesta A, Gutierrez C. 2005. Potential dependence of the saturation CO coverage of Pt electrodes The origin of the pre-peak in CO-stripping voltammograms. Part 1 Pt(lll). J Electroanal Chem 579 1-12. 

Figure 7.12 CO stripping experiment on a Pt(775) electrode decorated with different adatoms, as labelled, in 0.1 M HCIO4. The blank voltammogram is also included for comparison.

Figure 10.5 CO-stripping voltammograms (sweep rate 0.10 V s ) at pure Pt and stabilized Pt5gCo42 in 0.1 M HCIO4, and PtgoRu4o in 0.05 M H2SO4 at room temperature. The CO pre-adsorption was performed in CO-saturated solution at 0.075 V for 5 minutes. (From Wakisaka et al. [2006], reproduced by permission of the American Chemical Society.)...

Figure 12.5 CO stripping voltammogram with a CO- tee 0.1 M H2SO4 electrolyte. Compare the data in Fig. 12.4 the CO oxidation region begins at V = 0.43 V. After CO stripping, hydrogen adsorption/desorption peaks and the beginning of the Pt oxidation range are shown.

Figure 2.19 Linear sweep voltammograms of a platinum electrode immersed in N -saturated 0.5 M H2SO t showing the anodic stripping of adsorbed CO. The CO was adsorbed from the CO-saturated electrolyte for 10 minutes at the designated potential. The scan rate was 1 mV s The adsorption potential was (a) 0.05 V and (b) 0.4 V vs. NHE. Note the different electrode potential scales for the two plots. From Kunimatsu et at. (1986).

FIGURE 14.6 Typical stripping voltammograms for (a) nanocrystal-labeled antibodies and (b-f) magnetic bead-Ab-Ag-Ab-nanocrystal complexes, (b) Response for a solution containing dissolved ZnS anti-/32-microglobulin, PbS-anti-BSA, and CdS-anti-IgG conjugates (reproduced from [29] with permission). 

Fig. 35. Disk and ring voltammograms recorded during the oxidation of thin-layer Co-Al electrodeposits from a Pt-RRDE in pure 60.0 m/o AlCl3-EtMeImCl melt. These deposits were produced with a charge density of 425 mC cm 2 in melt containing 5.00 mmol L-1 M Co(II) at the following deposition potentials (—) 0.200, (—) 0.100, and ( ) 0 V. During stripping, the disk electrode was scanned at 0.002 V s 1, and Er was held at 0.500 V. The angular velocity of the RRDE was 104.7 rad s 1. Adapted from Mitchell et al. [44] by permission of The Electrochemical Society.

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