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Vinylimido complex

In the presence of trimethylphosphine or 4-dimethylaminopyridine, titanocene vinylimido complexes 84 are produced by treating the in situ generated titanocene-methy-... [Pg.495]

The reaction of titanocene-alkylidenes generated from thioacetals with nitriles followed by hydrolysis affords ketones. Like the reaction of titanocene-methylidene, this reaction may proceed via the azatitanacydobutene 87 and/or the vinylimido complex 88, which reacts with an organic halide to form an a-substituted ketone [80] (Scheme 14.37). [Pg.496]

See other pages where Vinylimido complex is mentioned: [Pg.496]    [Pg.496]    [Pg.216]    [Pg.496]    [Pg.496]    [Pg.216]    [Pg.163]   
See also in sourсe #XX -- [ Pg.496 ]

See also in sourсe #XX -- [ Pg.496 ]



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Titanocene vinylimido complexes

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