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Vinyl fluoride ions, decomposition

Vinylidenes have been transferred from a variety of precursors to olefins to produce methylenecyclopropanes . Because of ready intramolecular hydrogen shifts to give terminal acetylenes, the addition of vinylidene to olefins is rather limited to 2,2-disubstituted species. The methodologies so far developed include (1) gem-dibromides, 7, with MeLi, (2) vinyl halides " or vinyl triflates, 8 " with r-BuOK, (3) the fluoride ion promoted decomposition of vinylsilanes, 92 2,243 4 thermolysis of mercuric derivatives, 10, at 250 (5) decomposition of vinylazo compounds, 11, at 25 (6) the alkaline... [Pg.326]

See other pages where Vinyl fluoride ions, decomposition is mentioned: [Pg.65]    [Pg.52]    [Pg.470]    [Pg.196]    [Pg.148]    [Pg.498]    [Pg.562]    [Pg.989]    [Pg.462]   
See also in sourсe #XX -- [ Pg.97 , Pg.179 ]

See also in sourсe #XX -- [ Pg.97 , Pg.179 ]



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Fluorid-Ion

Fluoride ion

Vinyl fluorides

Vinyl ions, decomposition

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