Vibro-rotational coupling

UV-VIS spectrum (p. 280) vibrational energy (p. 281) vibrational function (p. 279) vibrational structure (p. 279) vibronic coupling (p. 318) vibro-translational coupling (p. 291) vibro-rotational coupling (p. 291) wave function measurement (p. 301)... [Pg.332]

The first three ( diagonal ) terms have a clear interpretation. These are the kinetic energy of the centre of mass, the kinetic energy of rotation, and the kinetic energy of vibrations. The three further terms ( non-diagonal ) denote the roto-translational, vibro-translational and vibro-rotational couplings. [Pg.243]

In yet another study in the pressure range 5-40 torr, but using a capacitively coupled rf discharge, the decomposition of NH3 followed an apparent zero order kinetics which was interpreted on the basis of a kinetic mechanism involving vibro-rotationally excited molecules. Figure 12 shows the degree of conversion of NHj as a function of the mean residence time within a tubular reactor. Simultaneous spectroscopic measurements at different positions along the reactor axis showed... [Pg.12]

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