Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Vector algebra linear combination

Just as a known root of an algebraic equation can be divided out, and the equation reduced to one of lower order, so a known root and the vector belonging to it can be used to reduce the matrix to one of lower order whose roots are the yet unknown roots. In principle this can be continued until the matrix reduces to a scalar, which is the last remaining root. The process is known as deflation. Quite generally, in fact, let P be a matrix of, say, p linearly independent columns such that each column of AP is a linear combination of columns of P itself. In particular, this will be true if the columns of P are characteristic vectors. Then... [Pg.71]

Next, if g is a subalgebra of the conformal algebra c(l,3) with a nonzero projection on the vector space spanned by the operators D. Kq. K. Kt. K, then the corresponding matrices are linear combinations of the matrices E and. Sj(v. That is why the matrix should be sought in the more general form... [Pg.282]

Exercise 8.10 In this exercise we construct infinite-dimensional irreducible representations of the Lie algebra su (2). Suppose k. is a complex number such that L in for any nonnegative integer n. Consider a countable set S = vo, Vi, 172,... and let V denote the complex vector space of finite linear combinations of elements of S. Show that V can be made into a complex... [Pg.278]

Such a definition can, evidently, be extended to any number of routes. It is clear that if A(1), A(2), A<3) are routes of a given reaction, then any linear combination of these routes will also be a route of the reaction (i.e., will produce the cancellation of intermediates). Obviously, any number of such combinations can be formed. Speaking in terms of linear algebra, the reaction routes form a vector space. If, in a set of reaction routes, none can be represented as a linear combination of others, then the routes of this set are linearly independent. A set of linearly independent reaction routes such that any route of the reaction is a linear combination of these routes of the set will be called the basis of routes. It follows from the theorems of linear algebra that although the basis of routes can be chosen in different ways, the number of basis routes for a given reaction mechanism is determined uniquely, being the dimension of the space of the routes. Any set of routes is a basis if the routes of the set are linearly independent and if their number is equal to the dimension of the space of routes. [Pg.191]

Multiplication of the Dirac characters produces a linear combination of Dirac characters (see eq. (4.2.8)), as do the operations of addition and scalar multiplication. The Dirac characters therefore satisfy the requirements of a linear associative algebra in which the elements are linear combinations of Dirac characters. Since the classes are disjoint sets, the Nc Dirac characters in a group G are linearly independent, but any set of N< I 1 vectors made up of sums of group elements is necessarily linearly dependent. We need, therefore, only a satisfactory definition of the inner product for the class algebra to form a vector space. The inner product of two Dirac characters i lj is defined as the coefficient of the identity C in the expansion of the product il[ ilj in eq. (A2.2.8),... [Pg.439]

In terms of linear algebra the reaction routes form a vector space. If in a set of reaction routes none can be represented as a linear combination of others then the routes of this set are linearly independent and a set of such routes is called the basis of routes. Although the basis of routes can be chosen in different ways the number of basis routes for a given reaction mechanism is determined in a unique way, being the dimension of the space of the routes. [Pg.112]

It is demonstrated that we can construct as many independent linear combinations L as there are columns in the effect matrix. From these linear combinations, we can calculate an estimate (bfi of the weight of the factors studied. The estimate of these effects b, is obtained by multiplying the elements in column Xj by the corresponding elements of the experimental response vector K. then calculating the algebraic sum and dividing it by the number of experiments. [Pg.477]

A complex is called short, if it is not longer than two. A mechanism is a second order mechanism, if all the reactant complexes are short and if there exists at least one of length two. A set of elementary reactions is said to be independent if there is no way of expressing any of the elementary reaction vectors as a linear combination of the others. In the opposite case the elementary reactions are said to be dependent. From this definition it is clear that the number of independent elementary reactions is the number of independent columns of y. But this number is called in linear algebra the rank of y rank(y). This number is usually denoted by S and is considered as the dimension of the stoichiometric space, i.e. the dimension of the linear... [Pg.23]

It is essential for the further procedure that the matrix of constitution coefficients be rearranged and modified so as to contain only H linearly independent columns the first H rows, representing a qualitative description of the basic constituents, must likewise be linearly independent. An essential condition of the selection of basic constituents is the fact, that they must include all elements. It is then possible to define the two sets of algebraic relationships balance relationships for every basic constituent, using the equations (5J2), and equilibrium relationships (5.34) for individual chemical conversions, expressed as linear combinations of row vectors of the basic constituents by the equations (5.33). [Pg.126]

Here A is an (m x C) formula matrix, N is a (C x 1) vector of mole numbers, and b is an (mg x 1) vector of constant elemental abundances. (Basics of linear algebra are reviewed in Appendix B.) The matrix A is known from the chemical formulae of the species present, and the abundances b are known from the amounts initially loaded into the reactor. But the mole numbers N are unknown. Moreover, the sets N that satisfy the balances (7.4.2) are not unique many different combinations of amounts of the given species (N) can produce the same elemental balances (b). This means that the formula matrix A is singular. [Pg.500]

Hence, Xj = -2 if X2 = 1 and X3 = 0. We have therefore found a combination of values for Xj, X2, and X3 that produce zero when multiplied by A. In the language of linear algebra, we have found a basis for the null space of A. The vector... [Pg.154]

The most efficient perception routines use a mix of breadth-first trace, linear algebraic combination of the resultant ring vectors, and graph reduction during processing. These routines perform ring perception in polynomial time rather than exponential. [Pg.2515]


See other pages where Vector algebra linear combination is mentioned: [Pg.280]    [Pg.269]    [Pg.204]    [Pg.106]    [Pg.105]    [Pg.78]    [Pg.31]    [Pg.174]    [Pg.97]    [Pg.330]    [Pg.542]    [Pg.193]    [Pg.230]    [Pg.55]    [Pg.280]    [Pg.557]    [Pg.3700]   
See also in sourсe #XX -- [ Pg.332 ]

See also in sourсe #XX -- [ Pg.332 ]




SEARCH



Algebra vector

Linear combination

Vector linear combination

© 2024 chempedia.info