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Uranium isocyanide complexes

The analogous uranium(III) compounds also show unusual reactivity patterns. For example, addition of COT to (Cp )3U yields a mixed metallocene dimer (18) bridged by a COT ligand in this reaction, the (Cp )3U complex has effectively acted as a formal three-electron reductant (equation 3)." A variety of substituted (Cp )3U complexes form adducts with CO and CNR (isocyanides) - these are rare examples of actinide metals with r-acidic ligands." Paramagnetic uranium alkyl complexes are active in a range of catalytic processes." ... [Pg.3593]

The reaction of (CH3C5H4)3U THF with organic azides and with organic isocyanides yields uranium imido (equation (22.17)) and isocyanato (equation (22.18)) complexes [32] ... [Pg.676]

See other pages where Uranium isocyanide complexes is mentioned: [Pg.81]    [Pg.81]    [Pg.333]    [Pg.267]    [Pg.333]    [Pg.205]    [Pg.198]    [Pg.214]    [Pg.31]    [Pg.1053]    [Pg.336]    [Pg.112]    [Pg.213]    [Pg.48]    [Pg.349]    [Pg.32]    [Pg.143]    [Pg.4200]    [Pg.123]    [Pg.373]   
See also in sourсe #XX -- [ Pg.81 ]



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Isocyanide complexes

Isocyanides complexes

Uranium complexes

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