Uranium hexamethoxide

Uranium hexamethoxide, photoelectron spectroscopy Xa scattered-wave calculations, relativistic... [Pg.412]

Following the use of exchange reactions between TiCU and Si(OEt)4/SiCl(OEt)3, Marks and co-workers" have shown that uranium hexamethoxide can be prepared in the direct reaction between UFg and an excess of MeSi(OMe)3 (Eq. 2.164). [Pg.50]

Apart from the monomeric methoxides of the metalloids (B, Si, Ge, As, and Te) which are very volatile and soluble in organic solvents, most of the metal methoxides (except niobium and tantalum pentamethoxides and uranium hexamethoxide) are comparatively nonvolatile and insoluble in common organic solvents. Attempts have been made to... [Pg.56]

Tetrakis(ethylthio)uranium, 3096 Titanium butoxide, 3730 Titanium(III) methoxide, 1317 Titanium tetraisopropoxide, 3579 Tungsten hexamethoxide, 2604 Zinc ethoxide, 1704... [Pg.224]

Tetrakis(ethylthio)uranium, 3090 Titanium butoxide, 3724 Titanium tetraisopropoxide, 3573 Titanium(III) methoxide, 1313 Tungsten hexamethoxide, 2600 Zinc ethoxide, 1698... [Pg.2416]

Jacob" has described a variation of this reaction by using Si(OMc3)4 for the synthesis of hexamethoxides of uranium, molybdenum and rhenium (Eq. 2.165). [Pg.50]

Only a few structures of homoleptic uranium alkoxides have been reported. The hexamethoxide [U(OMe)6] is a mononuclear molecule with an octahedral UOe fi amework. The mixed valency [U(iv), U(v)] complex [U2(jU.-OBu )3(OBu )6] has... [Pg.267]

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