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Unsymmetric Tetraorganogermanes Containing Halogen Substituted Olefins

New is a series of derivatives of fluorolefins and synthesis of haloolefins by dehalocarbene insertion reaction. The haloolefin substituted tetraorgano-germanes in Table 6 are prepared by methods from the following scheme. [Pg.29]

By-prod, in rxn. with Me3GeMn(CO)s with C2CIF3 under UV irradiation (872). [Pg.29]

with MegSnH at 55° Me3GeCF CHF + MegGeCH. CFa + Me3GeCH CHF + MegSnF [Pg.29]

MesSnH under UV irradiation - cis-M GeCF CHF + [Me3GeCF(SnMe3)CF2H] + McsGe-CHFCFaSnMeg + MegSnF (2209). [Pg.29]

A.1 UNSYMMETRIC TETRAORGANOGERMANES CONTAINING HALOGEN SUBSTITUTED OLEFINS... [Pg.29]

Table 6. Unsymmetric Tetraorganogermanes Containing Halogen-Substituted Olefins RnGeR 4-r... Table 6. Unsymmetric Tetraorganogermanes Containing Halogen-Substituted Olefins RnGeR 4-r...


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Halogen substitution

Halogenated olefin

Halogene-containing

Olefins halogenation

Substituted olefins

Tetraorganogermanes Containing Halogen

Unsymmetric

Unsymmetrical olefins

Unsymmetrically substituted

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