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Unimolecular rectification

Fig. 14 Aviram-Ratner proposed D-o-A molecule for unimolecular rectification... Fig. 14 Aviram-Ratner proposed D-o-A molecule for unimolecular rectification...
Metzger RM (1999) The prospects for unimolecular rectification. In Sasabe H (ed) Hyper-structured molecules I chemistry, physics, and applications. Gordon Breach Science Publishers, Amsterdam, pp 19-39... [Pg.82]

Unimolecular rectification was first measured in 1993 for a monolayer of hexadecylquinolinium tricyanoquinodimethanide 31 [122] (which is a... [Pg.807]

In Milestone Eight, unimolecular rectification was confirmed by Robert M. Metzger and coworkers for an LB monolayer of hexadecylquinolinium tricyano-quinodimethanide. Ci H33 Q-3CNQ, 1 (Fig. 11) sandwiched at first between oxide-bearing A1 electrodes (Fig. and later across oxide-free Au... [Pg.1531]

The asymmetric placement between the electrodes of the significant molecular orbital coefficients of the energy levels relevant for electron transfer. This is U (for unimolecular) rectification. [Pg.1531]

Although unimolecular rectification has been confirmed, there are still questions ... [Pg.1535]

Unimolecular rectification is now an accomplished experimental fact. Its utilization in practical devices may not be too far in the future. However, it is important to fully understand and control the ground and first excited states of molecules that exhibit rectification. [Pg.1869]

Metzger RM, Chen B, Hopfner U, Lakshmikantham MV, Vuillaume D, Kawai T, Wu X, Tachibana H, Hughes TV, Sakurai H, Baldwin JW, Hosch C, Cava MP, Brehmer L, Ashwell GJ (1997) Unimolecular electrical rectification in hexadecylquinolinium tricyano-quinodimethanide. J Am Chem Soc 119(43) 10455-10466... [Pg.35]

The interest in TTF and TCNQ begat a seminal theoretical proposal on one-molecule rectification (Aviram and Ratner, 1974) which started unimolecular, or molecular-scale electronics. [Pg.282]

R. M. Metzger, B. Chen, U. Hopfner, M.V. Lakshmikan-tham, D. Vuillaume, T. Kawai, X. Wu, H. Tachibana, T. V. Hughes, H. Sakurai, J. W. Baldwin, C. Hosch, M. P. Cava, L. Brehmer, G. J. Ashwell, Unimolecular Electrical Rectification in Hexadecylquinolinium Tricyanoquinodi-methanide JACS1997,119,10455-10466. [Pg.254]

Metzger R.M. Electrical rectification by a molecule The advent of unimolecular electronic devices. Acc. Chem. Res. 1999, 32. 950-957. [Pg.900]

See other pages where Unimolecular rectification is mentioned: [Pg.39]    [Pg.40]    [Pg.53]    [Pg.54]    [Pg.56]    [Pg.82]    [Pg.318]    [Pg.338]    [Pg.1855]    [Pg.1858]    [Pg.39]    [Pg.40]    [Pg.53]    [Pg.54]    [Pg.56]    [Pg.82]    [Pg.318]    [Pg.338]    [Pg.1855]    [Pg.1858]    [Pg.807]    [Pg.821]    [Pg.338]    [Pg.775]    [Pg.1536]    [Pg.1865]    [Pg.98]    [Pg.98]   
See also in sourсe #XX -- [ Pg.318 ]



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Rectification

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