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Ullman diaryl ether synthesis

This reaction is related to the Rosemound-von Braun Nitrile Synthesis, Ullman Diaryl Ether Synthesis, and Ullmann Acridine Synthesis. [Pg.1572]

Ullman reaction The synthesis of diaryls by the condensation of aromatic halides with themselves or other aromatic halides, with the concomitant removal of halogens by a metal, e.g. copper powder thus bromobenzene gives diphenyl. The reaction may be extended to the preparation of diaryl ethers and diaryl thio-ethers by coupling a metal phenolate with an aryl halide. [Pg.411]

Ullman reaction. Synthesis of biaryls by copper-induced coupling of aryl halides. Similar coupling of aryl halides with aroxides yields diaryl ethers. (A modification of the Fittig synthesis in which copper powder is used instead of sodium.)... [Pg.1298]


See also in sourсe #XX -- [ Pg.144 ]

See also in sourсe #XX -- [ Pg.144 ]




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