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Two conceivable situations

Remember reactions involving more than one step often have one step that is slow compared with the other steps, and the overall rate is limited by the rate of this step, and can be approximated to the rate of this slow step. When this occurs, the slow step is termed the rate-determining step. Not all reactions have a rate-determining step. Sometimes the individual reactions have comparable rates, and the overall rate cannot be approximated to the rate of any individual step. [Pg.82]

When k2 2 k there is always a build-up of intermediate to a very very low, but steady, value of the concentration, which remains almost constant at this value until reaction is virtually complete, when it falls back to zero. The build-up to the steady plateau often occurs so very rapidly that it can only be followed using the specialized techniques of fast reactions. Determination of the very low concentrations of the intermediate is also difficult, and often cannot be achieved, though the modem laser-induced fluorescence methods are helping here. [Pg.83]

These two situations show totally different behaviour, and the graphs demonstrate two points  [Pg.83]


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Situation

Situational

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