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Turbo Grignard reagent

Keywords Alkali-metal DeprotonatiOTi Magnesiate Synthesis Turbo-Grignard Reagents... [Pg.103]

While the Turbo-Grignard reagents are proficient at metal-halogen exchange, the amide-based Turbo-Hauser reagents are more useful in selective metal-hydrogen... [Pg.109]

Fig. 6 Synthetic protocols for forming Turbo-Grignard (D) and Turbo-Hauser reagents (A, B and C)... Fig. 6 Synthetic protocols for forming Turbo-Grignard (D) and Turbo-Hauser reagents (A, B and C)...
Fig. 15 Contrasting reactivity of Turbo-A vs. a conventional Grignard reagent... Fig. 15 Contrasting reactivity of Turbo-A vs. a conventional Grignard reagent...
It is yet an open question whether ate complexes simply represent a storage form of their constituents and thus ultimately mirror alkyllithium chemistiy or deploy a reactivity pattern of their own. Magnesiates are for sure infinitely more nucleophilic than any ordinary Grignard reagent. This "turbo effect" is also a characteristic of heteromagnesiates, in particular of the adducts composed of a diorganomagnesium and lithium chloride. [Pg.26]

See other pages where Turbo Grignard reagent is mentioned: [Pg.744]    [Pg.777]    [Pg.792]    [Pg.814]    [Pg.816]    [Pg.108]    [Pg.109]    [Pg.109]    [Pg.136]    [Pg.285]    [Pg.744]    [Pg.777]    [Pg.792]    [Pg.814]    [Pg.816]    [Pg.108]    [Pg.109]    [Pg.109]    [Pg.136]    [Pg.285]    [Pg.366]    [Pg.114]   
See also in sourсe #XX -- [ Pg.103 , Pg.108 ]



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