Tungsten , halocarbonyl complexes seven-coordinate halocarbonyls

This article is concerned with six- and seven-coordinate halocarbonyl complexes of molybdenum(II) and tungsten(II) (Section II), of which earlier reviews by Colton et al.2 on substituted halocarbonyls of group 6 transition metals and on steric effects in substituted halocarbonyls of molybdenum and tungsten3 have been published. Also, reviews on the structures of seven-coordinate compounds by Drew in 19774 and by Melnik and Sharrock in 1985s contain relevant material. 

SIX- AND SEVEN-COORDINATE HALOCARBONYL COMPLEXES OF MOLYBDENUM(II) AND TUNGSTEN(II)... 

Thus far, the reactions of the diiodo-complexes [MI2(CO)3(NCMe)2] with alkynes have been described. In this section the reactions of other seven-coordinate molybdenum(II) and tungsten(II) halocarbonyls with alkynes are described. 

Six- and Seven-Coordinate Halocarbonyl Complexes of Molybdenum(II) and Tungsten(II). 47... 

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See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

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