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Tungsten dicarbonyl nitrosyl

Dicarbonyl Nitrosyl Ompkxes Chromiwn, Molybdenum, and Tungsten 197... [Pg.197]

O3NSC7HS, l,2-Benzisothiazol-3(2//)-one, 1,1-dioxide, chromium and vanadium complex, 27 307, 309 O3NWC7H5, Tungsten, dicarbonyl(i -cyclopentadienyl)nitrosyl-, 28 196 03N3MoC,2H, Molybdenum,... [Pg.430]

The chemistry of the dicarbonyl(7 -cyclopentadienyl)nitrosyl and the chloro-(i7 -cyclopentadienyl)dinitrosyl complexes of chromium, molybdenum, and tungsten [i.e., fT -CsHs)M(CO)j(NO)] and [(i7 -CsHs)M(NO)2Cl] has not been studied extensively, partly because of the various difficulties associated with their preparation. The procedures described below are of general applicability to all three metals and lead to the desired compounds in high yields. The carbonyl nitrosyl complexes are the synthetic precursors of the chloro nitrosyl complexes and so their preparation is described first. [Pg.127]

A. DICARBONYL(t -CYCLOPENTADIENYL)NITROSYL complexes of CHROMIUM, MOLYBDENUM, AND TUNGSTEN... [Pg.127]

The preparations of all three (tj -CsH5)M(CO)2(NO) complexes from their corresponding [(tj -CsHs)M(CO)3] anions are similar. The experimental procedure, using the tungsten complex (dicarbonyl(i7 -cyclopentadienyl)nitrosyl-tungsten) as a typical example, is given below. [Pg.128]


See other pages where Tungsten dicarbonyl nitrosyl is mentioned: [Pg.379]    [Pg.392]    [Pg.425]    [Pg.461]    [Pg.603]    [Pg.127]    [Pg.129]    [Pg.603]    [Pg.276]    [Pg.196]   
See also in sourсe #XX -- [ Pg.18 , Pg.127 ]

See also in sourсe #XX -- [ Pg.18 , Pg.127 ]

See also in sourсe #XX -- [ Pg.28 , Pg.196 ]

See also in sourсe #XX -- [ Pg.28 , Pg.196 ]




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