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Tungsten complexes hexanuclear clusters

A few cluster complexes with fused triangles of molybdenum or tungsten have been reported. They are tetranuclear and hexanuclear cluster complexes, which may be viewed also as having fused incomplete cu-banes of M3E4. [Pg.75]

The lower nuclearity clusters [Mo5Cl13]2 were isolated from MoCls in AlCl3/KCl/BiCl3/Bi melts that led to the hexanuclear species (17). This is the only intermediate isolated from reaction mixture that produces the Mo6C18 4+ core. Solution chemistry has yielded Mo2, Mo3, and Mo4 halide species from mononuclear molybdenum complexes, suggesting that a nucleation process similar to that proposed for the tungsten systems may take place during the formation of hexanuclear molybdenum clusters (18-22). [Pg.5]


See other pages where Tungsten complexes hexanuclear clusters is mentioned: [Pg.240]    [Pg.36]    [Pg.3311]    [Pg.171]    [Pg.562]    [Pg.11]    [Pg.562]   
See also in sourсe #XX -- [ Pg.1011 ]

See also in sourсe #XX -- [ Pg.3 , Pg.1011 ]




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