Trichloroethoxycarbonyl Troc

Triton X-100 octyl phenol ethoxylate Troc 2,2,2-trichloroethoxycarbonyl... 

Troc = 2,2,2-trichloroethoxycarbonyl Figure 9.72. Enantioselective amination of enolsilanes. 

SCHEME 3.11 Applications of trichloroacetimidates in glycosidic bond formation. Troc, 2,2,2-trichloroethoxycarbonyl. 

SCHEME 14.1 Synthesis of lipids I and II by VanNieuwenhze et al. Bn, benzyl CDI, l,l -carbonyldiimidazole DBU, l,8-diazabicyclo[5.4.0]undec-7-ene DIPEA, diisopropylethyl-amine EDC, l-ethyl-3-(3-dimethylaminopropyl)carbodiimide NHS, A-hydroxysuccinimide Pyr, pyridine TFA, trifluoroacetyl Troc, 2,2,2-trichloroethoxycarbonyl. 

Abbreviations Ac acetyl AIBN azobisisobutyronitrile All allyl Bn benzyl Bz benzoyl ClAc chloroacetyl DAST diethylaminosulfur trifluoride DBU l,8-diazabicyclo[5.4.0]-undec-7-ene DDQ 2,3-dichloro-5,6-dicyano-/)-benzoquinone DMDO dimethyldioxirane DMTST dimethyl(methylthio)sulfonium trifluoromethanesulfonate Fmoc 9-fluorenyl-methoxycarbonyl HDTC hydrazine dithiocarboxylate IDCP iodonium di-collidine perchlorate Lev levulinoyl MBz 4-methylbenzoyl Me methyl MEK methyl ethyl ketone MP 4-methoxyphenyl NBS iV-bromosuccinimide NIS A-iodosuccinimide Pent n-pentenyl Pfp pentafluorophenyl Ph phenyl Phth phthaloyl Piv pivaloyl PMB 4-methoxybenzyl TBAF tetrabutylammonium fluoride TBDMS tcrt-butyldimethylsilyl TBDPS tert-butyldiphenylsilyl TCA trichloroacetyl TES triethylsilyl Tf trifluoromethanesulfonyl TMS trimethylsilyl Tol 4-methylphenyl Tr trityl Troc 2,2,2-trichloroethoxycarbonyl Ts tosyl. 

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