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Tris ligand bending

Figure 23. View looking down the threefold axis of a TP tris(dithiolene) complex, (a) The HOMO orbital is comprised of the ligand Uy orbitals centered about the dz2 metal orbital. (b) Energy minimization of the HOMO occurs if ligand bending takes place improving the bonding orbital overlap. [Figure adapted from (372).]... Figure 23. View looking down the threefold axis of a TP tris(dithiolene) complex, (a) The HOMO orbital is comprised of the ligand Uy orbitals centered about the dz2 metal orbital. (b) Energy minimization of the HOMO occurs if ligand bending takes place improving the bonding orbital overlap. [Figure adapted from (372).]...
Rationalization for why ligand bending takes place in some tris(dithiolene) complexes has been addressed recently by Campbell and Harris (372) and previously by others (7, 357). In TP structures, the bend is thought to result from a second-order Jahn-Teller distortion where the highest occupied molecular orbital (HOMO) is lowered in energy as a result of improved overlap between the ligand nv and the metal dz2 orbitals as depicted in Fig. 23 (372). [Pg.89]

See other pages where Tris ligand bending is mentioned: [Pg.56]    [Pg.88]    [Pg.92]    [Pg.92]    [Pg.95]    [Pg.56]    [Pg.88]    [Pg.92]    [Pg.92]    [Pg.95]    [Pg.127]    [Pg.1085]    [Pg.89]    [Pg.90]    [Pg.124]    [Pg.184]    [Pg.89]    [Pg.90]    [Pg.124]    [Pg.184]    [Pg.230]    [Pg.9]    [Pg.285]    [Pg.134]    [Pg.452]    [Pg.121]    [Pg.285]    [Pg.572]    [Pg.230]    [Pg.2924]    [Pg.3684]    [Pg.574]    [Pg.114]    [Pg.474]   
See also in sourсe #XX -- [ Pg.88 , Pg.89 , Pg.90 , Pg.91 ]

See also in sourсe #XX -- [ Pg.88 , Pg.89 , Pg.90 , Pg.91 ]



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