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Triphenylsilyl potassium

Triphenylsilyl potassium, 141 Tris(dimethylamino)sulphonium difluoro-trimethylsilicate, 136... [Pg.170]

Triphenylsilyl potassium adds like triphenylmethyl sodium to formaldehyde, giving the expected alcohol. [Pg.212]

One of the very earliest syntheses of an acyl silane involved the reaction of benzoyl chloride with triphenylsilyl potassium at low temperature (Scheme 6)2. The very low yield of benzoyl triphenylsilane (6%) obtained, and the similar yields of... [Pg.1608]

The first preparation of such an alkali-organosilicon compound was made by Kraus391 and Benkeser31. Gilman and Wu224 first cleaved hexaphenyl-disilane with potassium/sodium alloy and obtained triphenylsilyl potassium as a dark solution in ether. [Pg.17]

The preparation of the pure compound was not possible. However, in solution, asymmetric disilanes are formed if triphenylsilyl potassium is treated with organosilicon halides. Some examples of these reactions are given in the following equations ... [Pg.18]

See other pages where Triphenylsilyl potassium is mentioned: [Pg.159]    [Pg.159]    [Pg.165]    [Pg.19]    [Pg.285]    [Pg.265]    [Pg.28]    [Pg.141]    [Pg.145]    [Pg.165]    [Pg.615]    [Pg.37]    [Pg.610]   
See also in sourсe #XX -- [ Pg.141 ]

See also in sourсe #XX -- [ Pg.141 ]

See also in sourсe #XX -- [ Pg.141 ]



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Triphenylsilyl

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