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Trinuclear complexes, photochemistry

Table V summarizes the key photochemistry of trinuclear metal-metal bonded complexes. The first noteworthy photochemical study of trinuclear complexes concerns Ru3(CO)j2. This species was found to undergo declusterification to mononuclear fragments when irradiated in the presence of entering ligands such as CO, PPh3,°T ethylene. The intriguing finding is that thermal reaction of Ru3(C0)12 with PPh3 results in the substitution product indicated in equation (18) whereas irradiation yields the mononuclear species given by equation (19) (57). These results... Table V summarizes the key photochemistry of trinuclear metal-metal bonded complexes. The first noteworthy photochemical study of trinuclear complexes concerns Ru3(CO)j2. This species was found to undergo declusterification to mononuclear fragments when irradiated in the presence of entering ligands such as CO, PPh3,°T ethylene. The intriguing finding is that thermal reaction of Ru3(C0)12 with PPh3 results in the substitution product indicated in equation (18) whereas irradiation yields the mononuclear species given by equation (19) (57). These results...
The trinuclear M3(CO)12 (M = Fe, Ru, Os) complexes have received some attention from experimentalists, but neither the electronic spectroscopy nor the photochemistry of these complexes have been investigated in detail. The recent report107)... [Pg.76]

See other pages where Trinuclear complexes, photochemistry is mentioned: [Pg.88]    [Pg.102]    [Pg.257]    [Pg.115]    [Pg.54]    [Pg.103]    [Pg.129]    [Pg.154]    [Pg.360]    [Pg.367]   
See also in sourсe #XX -- [ Pg.102 , Pg.103 ]



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