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Triglyme, nickel complexes

The complexes are very soluble in methanol, ethanol, butanol, methyl Cellosolve (2-methoxyethanol), and ethyl Cellosolve (2-ethoxyethanol), and to a fair degree, quite soluble in 1,2-dimethoxyethane and di- and triglyme. They are initially quite soluble in tetrahydrofuran, acetone, pyridine, nitro-methane, acetonitrile, dimethyl sulfoxide, and iV,A/-dimethyl-formamide, but usually precipitation of the nickel halide-solvent complex occurs if attempts are made to prepare moderately concentrated solutions in these solvents. They are only very slightly soluble, or are quite insoluble in dioxane, ethyl ether, hexane, dichloromethane, ethyl acetate, and methyl- and butyl-cellosolve acetate (2-methoxyethyl and 2-butoxyethyl acetate). [Pg.164]


See also in sourсe #XX -- [ Pg.13 , Pg.161 , Pg.162 ]

See also in sourсe #XX -- [ Pg.13 , Pg.161 , Pg.162 ]

See also in sourсe #XX -- [ Pg.13 , Pg.161 , Pg.162 ]




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Triglyme

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