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Trifluorophosphine alkenes

A variety of synthetic routes to monoene and polyene tri-fluorophosphine-transition metal complexes have been devised. Direct photochemically induced reaction of a metal-PF3 complex with an activated alkene or diene (method A) has proved useful only for iron, the products being either [Fe(PF3)4(alkene)J or [Fe(PF3)3(diene)] (194). Mixed carbonyl-trifluorophosphine complexes of the type [Fe(PF3)x(CO)3 x(diene)] result from either thermal or photochemical reactions of dieneiron carbonyl complexes and PF3 (52, 53) (method B). The compounds are fluxional. [Pg.77]

Alkene Transition Metal Complexes Containing Trifluorophosphine... [Pg.83]

See other pages where Trifluorophosphine alkenes is mentioned: [Pg.148]    [Pg.155]    [Pg.200]    [Pg.261]    [Pg.266]   
See also in sourсe #XX -- [ Pg.29 , Pg.77 , Pg.80 , Pg.81 , Pg.82 , Pg.83 , Pg.84 ]



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Trifluorophosphine

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