Trifluoromethyl sulfur pentafluoride

A growing body of evidence indicates that human activities are causing the earth to warm up. This so-called greenhouse effect is due principally to the release of gases such as methane and carbon dioxide into the atmosphere that act to hamper the radiation of heat into space. Now scientists have found a gas in the atmosphere that is the new champion of greenhouse gases. This gas is trifluoromethyl sulfur pentafluoride (SF5CF3), which has the structure... 

CFeS, Trifluoromethyl sulfur pentafluoride (gas-ed), 22, 554 CHF3O3S 0.5 H2O, Trifluoromethanesulphonic acid hemihydrate, 41B, 72... 

In the reaction with bis(trifluoromethyl) trioxide (10), addition of both CF30 and CF300 groups to the sulfur tetrafluoride molecule occurs to give a mixture of . v-(trifluoromethoxy)(tri-fluoromethylperoxy)sulfur tetrafluoride, s-bis(trifluoromethoxy)sulfur tetrafluoride (11) and (trifluoromethoxy)sulfur pentafluoride.215... 

Tetrakis(trifluoromethyl)dithietane is generated by dimerization of hexa-fluorothioaeetone which is prepared in situ from hexafluoiopropylene with potassium fluoride and sulfur [189] or with sulfur and antimony pentafluoride [190] (equation 27)... 

The sulfur trifluoride compounds are useful as selective agents for conversion of carbonyl and carboxyl groups to difluorometh-ylene 7 and trifluoromethyl groups,3 4 respectively, and as intermediates for synthesis of arylsulfur pentafluorides.3 8... 

Tris(2,4-pentanedionato)molybdenum(III), synthesis 39 Potassium tetraoxalatouranate(IV), synthesis 40 Sulfur chloride pentafluoride, synthesis 41 Trifluoromethyl hypofluorite, synthesis 42 Ammonium perrhcnate, synthesis 43... 

Phosphorus pentafluoride Polarine oil Selenium mustard Silicon tetrafluoride Strontium chlorate Strontium permanganate Sulfur chloropentafluoride Sulfur dichloride Sulfur hexafluoride Sulfur monochloride Titanium tetrachloride Thiocarhonyl dichloride Thionyl fluoride Thioptiosgene Triethyl aluminum Trifluoromethyl iodide Triisohutylaluminum Trimethylaluminum Vanadium tetrachloride Vincennite Vinyl bromide Vinylmagnesium bromide Xenon difluoride Zinc arsenide... 

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