Trifluoroacetaldehyde, photolysis

The photolysis of trifluoroacetaldehyde at a wavelength of 3130 A. has been shown by Dodd and Smith68 to follow a reaction scheme... [Pg.177]

Similarly, the perfluoroacyl radical CF3C (—O)203 was obtained by photolysis of a cyclopropane solution containing dw-butyl peroxide and trifluoroacetaldehyde below -80 °C after abstraction of the aldehydic hydrogen atom, the trifluoroacetyl radical is formed. It decarbonylates above -80 °C and exhibits a coupling of 11.54 G with three equivalent 19F nuclei. [Pg.316]

The e.s.r. spectrum of the trifluoroacetyl radical, generated by photolysis of a cyclopropane solution of trifluoroacetaldehyde and di-t-butyl peroxide at temper-... [Pg.155]

CF3-C0-N(0)Bu formed by photolysis of a mixture of trifluoroacetaldehyde and di-t-butylperoxylate in the presence of the spin trap t-nitrosobutane at room temperature. [Pg.156]

Richter, H.R., J.R. Sodeau, and 1. Barnes (1993), The photolysis and chlorine-initiated photooxidation of trifluoroacetaldehyde, STEP-HALOLSIDE/AFEAS Workshop, Dublin, 23—25 March, pp.182—188. [Pg.1454]

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