Trideca-1,2-diene

Undeca- diene 1,5-Trideca- diene 1,11-Octadeca- diene Limonene 8-Cyclohexyl-1,5-octadiene... 

Interestingly, reaction of aryl halides with long chain Q ,allylpalladium intermediates, which are trapped by nucleophiles. Treatment of 3-iodopyridine (362) with 1,12-trideca-diene (363) in the presence of amine 364 produced a mixture of 365 (62 %) and 366 (13 %). The reaction took 4 days showing that the elimination and readdition of H-Pd-X occurred back and forth many times along the long carbon chain, and was terminated by the formation of the 7r-allylpalladium intermediate [145],... 

Ac [10297-61-7]. l-Acetoxy-10 propyl-5y9-trideca-diene. Propylure. Sex attractant of the female pink bollworm moth Pectinophora gossypelia. Liq. Bpo 5 110-120 . 

The early Escherunoser-Stork results indicated, that stereoselective cyclizations may be achieved, if monocyclic olefins with 1,5-polyene side chains are used as substrates in acid treatment. This assumption has now been justified by many syntheses of polycyclic systems. A typical example synthesis is given with the last reaction. The cyclization of a trideca-3,7-dien-11-ynyl cyclopentenol leads in 70% yield to a 17-acetyl A-norsteroid with correct stereochemistry at all ring junctions. Ozonolysis of ring A and aldol condensation gave dl-progesterone (M.B. Gravestock, 1978 see p. 279f.). 

The oxidation of oxepins generally results in cleavage of the ring. An exception is the bridged oxepin derivative diethyl 3,6-hexanooxepin-4,5-dicarboxylate which is oxidized with potassium permanganate in the presence of potassium carbonate to give diethyl 8-hydroxy-9-oxo-10-oxabicyclo[6.3.2]trideca-l(ll),12-diene-12,13-dicarboxylate in 39% yield (mp 98 C).130... 

C4O-C4N2-C4NO2 8,13-Dioxa-2,6-diaza-tricyc lo[8.2.1.02,7]trideca-3,6-diene 14, 204... 

Z,Z)-Trideca-4,7-dien-l-ol (Z,Z)-Tetradeca-5,8-dien-l-ol (Z,Z)-Pentadeca-6,9-dien-1 -ol... 

Tridecan-2-one Lf Trideca-trans-3-trans-7-diene-2-12-dione, 6-hydroxy-9-iso-propyl-6-methyl FI 0.04 ... 

Hi 3-Methoxy-l l-phenyl-2,6,10,12-tetraoxa-5,7-diaza-tricyclo [7.4.0.0 s]trideca-4,6-dien-5-oxid, 58%... 

Oxabicyclo[8.2.1 ] trideca-l( 12), 10-diene or 1,14-epoxycy clod odeca-1,3-diene ... 

The silica gel column was eluted starting with hexane (70 mL), followed by 2% ethyl acetate/hexane (100 mL) 5% ethyl acetate/hexane (100 mL) 10% ethyl acetate/hexane (600 mL). The fractions were monitored with 20% ethyl acetate/hexane, using silicon 7 GF plates (purchased from Analtech, Inc.), thickness 250 xm, 20 cm long x 5 cm wide. The plates were sprayed with 3% ceric sulfate and heated at 350°C to detect dienone and monoenone. Alternatively, silica gel 60 F-254 plates (purchased from EM Laboratories, Inc.), thickness 25 mm, 20 cm long x 5 cm wide may be used. Detection may be made with ultraviolet light. The ratio of 1 g of crude dienone to 15 g of silica gel is adequate for obtaining pure spiro[5.7]trideca-l,4-dien 3 one. 

Dithia-9,11, 12-t riaza-tet racy e-lo 6.3.1.13-6.02,7]trideca-ll2,4,8,10-tetraen 10-Diethyl-amino- E9c, 844 (Dien + Hetaren)... 

Tricyclol5.4.2.0 -7 trideca-9,12-diene E17f, 738 (Tricyclo-thiolan-S,S-dioxid/A)... 

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