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Triborane 7 Adducts

M. Kameda and G. Kodama, Inorg. Chem., 1980, 19, 2288. Cleavage reaction of penta-borane(9). Formation of a new hypho triborane adduct. [Pg.62]

Triborane B3H7 can be readily generated from B3H8 by reaction with a nonoxidizing protic acid in the presence of an ether. Under these conditions it must be stabilized as a Lewis acid base adduct. The 1 1 THF adduct of B3H7 is quite stable and is most often used for further reactions. The ether may be readily replaced by stronger bases such as dimethylamine [22] ... [Pg.52]

While the THF adduct of triborane(7) reacts with Bu -B=N-Bul by hydrobora-tion to produce a /<-aminodiborane (see Section 2.1.4.1) the analogous reaction... [Pg.62]

C. The Preparation and Chemistry of the Dimethyl Ether Adduct of Triborane(7)j Diborane(4) Adducts... [Pg.34]

The dimethyl ether adduct of triborane(7) 124> has been prepared by the cleavage of tetraborane(lO) at room temperature according to the equation ... [Pg.34]

Bis(trifluorophosphine)-diborane 4) (m.p. —114.3°C) is obtained from trifluorophosphine and the dimethyl ether adduct of triborane (7)... [Pg.441]

See other pages where Triborane 7 Adducts is mentioned: [Pg.33]    [Pg.52]    [Pg.712]    [Pg.52]    [Pg.56]    [Pg.126]    [Pg.33]    [Pg.33]    [Pg.37]    [Pg.38]   


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