Triaminoguanidinium azotetrazolate

Fig. 2.10 Molecular structures of triaminoguanidinium azotetrazolate (TAGzT) and hydrazinium 5-aminotetrazolate (HyAt).

Fig. 12.2 Structures of hydrazinium azotetrazolate (HZT) and triaminoguanidinium azotetrazolate (TAGzT).

Other 5,5 azotetrazolates reported include salts that contain cations such as bis(hexahydropyridaziniiun) (67g), bis[N-amino-l-azonia-cyclohex-ane] (67h), bis[ethylene-dihydrazinium (+1)] (67i), ethylenedihydrazinium (+2) (67j), bis[N-amino-N, M -dimethyl-guanidinium] (67k), diguanidinium (671), bis(triaminoguanidinium) (67m), and bis(azidoformamidinium) (67n) (Fig. 3) [76,79]. These salts were characterized by IR, Raman, and NMR spectroscopy, and elemental analyses X-ray crystal structures of 66a,c,e, 67a,e,j, and 671 were determined. 

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