6.1 ,6 -triamino-6,1 ,6 -trideoxy

WATER AND PROTON EXCHANGE PROCESSES ON METAL IONS TACI = 1,3,5-triamino-1,3,5-trideoxy-cis-inositol =... 

A bis(alkoxide) complex is afforded by the reaction of 1,3,5-triamino-1,3, 5-trideoxy-a s-inositol [HOC(H)=C(H)NH2]3 [117] with AICI3 [118]. The ion-separated tribromide, Al[OC(H)=C(H)NH3]3 3Br [Al-0 = 1.894(2)-1.912(2) A], contains a cationic component which incorporates two neutral, tripodal 0-centred ligands and so shows a hexa(oxygen) coordination sphere for the metal centre. In a similar vein, mixed 0,0, N-tridentate behaviour has been noted for the monoanionic 1 2 polycarboxylate complex Al[(02CCH2)2NMe]2 (for which the separate counter-ion is NH4 ) [119]. 

Complexes of the ligand 1,3,5-triamino-1,3,5-trideoxy-cis-inositol and its derivatives. These ligands act as N3 donors towards both iron(II) and high-spin iron(III), although ring inversion could make a facially coordinating 03 donor set available (93,94). 

Besides these, to one metal atom coordinated m-inositol complexes, there are two related fields of research. One is the complex coordination of metal atoms to the polyaminoalcohols, especially l,3,5-triamino-l,3,5-trideoxy-d5 -inositol, since the amino group can either act as additional donors for metal binding or serve as internal bases, facilitating the deprotonation and coordination of the hydroxyl groups [107]. 

J. Hildesheim, J. Cleophax, A.-M. Sepulchre, and S. D. Gero, Displacements in methylfu-ranosides. Synthesis of derivatives of 2,3,5-triamino-2,3,5-trideoxy-D-arabinose and -d-xylose, Carbohydr. Res., 9 (1969) 315-322. 

Examples myo-Inositol 1,3,5-Triamino-1,3,5-trideoxy-scyZZo-inositol... 

Methyl 2,3,5-triamino-2,3,5-trideoxy-p-D-arabinofuranoside, T-134 Methyl 3-trichloroacetamido-2,3,6-trideoxy-a-L-ri6o -hexopyranoside, AM62... 

Methyl (methyl 5-acetamido-4,7,8,9-tetra-0-acetyl-3,5-dideoxy-a-D-glycero -D-galacto -2-nonulopyranosid)onate, A-20 Methyl 2,3,5-triacetamido-2,3,5-trideoxy-p-D-arabinofuranoside, T-134 Methyl 2,3,5-triamino-2,3,5-trideoxy-p-D-arabinofuranoside, T-134... 

Inorganic Derivatives.- 1,6-Anhydro 2-chloro-2,4-dideoxy-4-(diphenylphosphoryl)-P-D-glucopyranose, the P-in-the-ring sugar analogues (27) and (28)," the natural arsenic-containing riboside (29), methyl 4,6-0-benzylidene-3-deoxy-3-C-triphenylstannyl-a-D-altropyranoside, two isomeric chromium(III) complexes with 1,3,5-triamino-1,3,5-trideoxy-cw-inositol in the one structure, the vanadium(in) complex (30),and the platinum(Il)-dithiocarbamate complex (31). ... 

---