TRIALKYLANTIMONY HALIDES

Textile clothing static charges, 394 Theory without detailed thought, 394 Thermal explosions, 394 Thermal stability of reaction mixtures and systems, 394 Thermite reactions, 395 Thermochemistry and exothermic decomposition, 396 Thiatriazoles, 400 Thionoesters, 401 Thiophenoxides, 401 Thorium furnace residues, 401 Tollens reagent, 401 Toxic hazards, 402 Trialkylaluminiums, 402 Trialkylantimony halides, 403 Trialkylbismuths, 403... 

Like triorganoantimony(V) halides, derivatives of this class had also been prepared in the middle of nineteenth century169-171). The procedure adopted, which is still the principal method for preparing the tetraalkyl antimony halides involves the quaternization of trialkylantimony with an alkyl halide13,172). Since the triarylantimony as well as diaryl-alkylantimony can not be quatemized by alkyl halides, other methods13,21,23,98,173 179 e.g., the reaction of triphenylstibine, chlorobenzene and anhydrous aluminium chloride179), have been utilized to prepare these derivatives. 

Trialkylantimony compounds react with alkyl halides to form the corresponding tetraalkylantimony salts (equations and 211 ). 

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