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Transmetalation of Organoboron and Organoaluminium Reagents

Direct transmetalation of organoboranes to organocopper reagents is not a general reaction. Because of their similar bond energies and electronegativities, this transmetalation is limited to the preparation of alkenylcopper and unfunctionalized [Pg.51]

In the presence of a polar cosolvent such as hexamethylphosphoric triamide (HMPA), it is possible to generate the fluorine-substituted copper compound 57, [Pg.52]


See other pages where Transmetalation of Organoboron and Organoaluminium Reagents is mentioned: [Pg.51]    [Pg.51]    [Pg.51]    [Pg.53]    [Pg.51]    [Pg.51]    [Pg.53]    [Pg.51]    [Pg.51]    [Pg.51]    [Pg.51]    [Pg.53]    [Pg.51]    [Pg.51]    [Pg.53]    [Pg.51]   


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And transmetallation

Organoaluminium

Organoaluminiums

Organoboron

Organoboron reagents

Organoboronates

Organoboronic reagents

Organoborons

Transmetalation

Transmetalations

Transmetallating reagent

Transmetallation

Transmetallation of organoboron

Transmetallations

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