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Transitions length change with increased

Earlier studies of macromolecules with flexible, non-mesogenic side-chains had revealed that the transition properties change with increasing side-chain length from typical polymeric behavior to that of the small molecule which corresponds to the side chain 72,73). With short side-chains and proper backbone geometry (tacticity),... [Pg.25]

A number of polyfalkyi methacrylates) are available. Explain how the glass transition temperature will change with increasing alliyl chain length ... [Pg.67]

Uniaxial stress-induced phase transition in gels [29]. The changes in diameter and length of cylindrical N-isopropylacrylamide gels were measured under uniaxial stress along the axis. The transition temperature and discontinuity were increased with increasing stress, which indicates the possibility of the... [Pg.202]

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Length change

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