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Transition states thermodynamics versus kinetics

Energy Barriers in Chemical Reactions The Transition State and Activation Energy Reaction Mechanism The Hammond Postulate Thermodynamics versus Kinetics... [Pg.331]

Kinetic versus thermodynamic control. A plot of Gibbs free energy versus reaction coordinate for Step 2 in the electrophilic addition of HBr to 1,3-butadiene. The resonance-stabilized allylic carbocation intermediate reacts with bromide ion by way of the transition state on the left to give the 1,2-addition product. It reacts with bromide ion by way of the alternative transition state on the right to give the 1,4-addition product. [Pg.871]

See other pages where Transition states thermodynamics versus kinetics is mentioned: [Pg.505]    [Pg.291]    [Pg.3]    [Pg.227]    [Pg.230]    [Pg.532]    [Pg.34]    [Pg.721]    [Pg.149]    [Pg.511]    [Pg.248]    [Pg.309]    [Pg.393]    [Pg.206]    [Pg.402]    [Pg.398]    [Pg.95]    [Pg.102]   


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Kinetic transitions

Kinetic/thermodynamic

Kinetics (versus

Kinetics versus thermodynamics

State, thermodynamic

Thermodynamic Versus Kinetic

Thermodynamics transitions

Thermodynamics, kinetics

Transition, kinetics

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