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Transition metal nitrosyl complexes energy

Many transition metal nitrosyl complexes release NO upon photolysis. For example, NO release was observed from Mo(CO)(NO)(dppe)(dtc), where dtc = S2CNMe2, and dppe = diphenyl-phosphino-ethane. The lowest energy absorption band of this compound, at 520 nm, has been assigned to a LLCT (dtc NO ) transition. Photolysis into the low energy side of this band (2irr = 546 nm) in benzene solutions results in loss of NO ((/> = 0.0018) [84]. [Pg.130]

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Complex energy

Energy metals

Energy, transition energies

Metal nitrosyls

Metallic Nitrosyls

Nitrosyl complexes

Nitrosyls complexes

Transition energies

Transition metal nitrosyl complexes