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Transition from bonding to antibonding

Electronic transitions from bonding to antibonding molecular orbitals are often encountered. In this case the potential energy curve for the ground state will be quite different from that of the excited state because less bonding electron density is found in the excited state. An example is the transition from the ground state of NO+ ion to the first excited state, as shown in Fig 14.55. [Pg.682]

Transitions from -bonding to 7r-antibonding ligand orbitals, called ligand-centred (LC) or internal ligand (IL)... [Pg.25]

Transitions from essentially non-bonding to antibonding ri-orbitals localized in central atom, called metal-centred (MC) or ligand field (LF) or d-d transitions (characterized by the ligand field splitting energy, A)... [Pg.25]

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Antibond

Antibonding

Bonding antibonding