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Transient interpenetrating network

When the monomer concentration exceeds c [see Eq. (112) and Fig. 38], the different polymer molecules are no longer separated but interpenetrate each other forming a transient network of lifetime xg. At constant temperature this network structure is characterized by a concentration-dependent correlation length (c), which may be considered as the mean mesh size of the pseudo gel. [Pg.109]

If we now Increase the concentration beyond the colls Interpenetrate more and more and the concentration fluctuations. In the dilute regime taking place over distances of order a. become smaller. A simple picture of the semldllute solution is that of a transient network with an average mesh size between Interchain crossings the quantity Is called the correlation length (see also sec. I.7.7c). A mesh volume of size 5 (also called a "blob" contains N. [Pg.622]


See other pages where Transient interpenetrating network is mentioned: [Pg.87]    [Pg.87]    [Pg.103]    [Pg.16]    [Pg.20]    [Pg.346]    [Pg.218]    [Pg.216]    [Pg.210]    [Pg.102]    [Pg.103]    [Pg.1794]    [Pg.68]    [Pg.247]    [Pg.12]    [Pg.49]    [Pg.755]   
See also in sourсe #XX -- [ Pg.87 ]




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