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Transference numbers abnormal

Abnormal Transference Numbers.—In certain cases, particularly with solutions of cadmium iodide, the transference number varies markedly with concentration, and the values may become zero or even apparently negative the results for aqueous solutions of cadmium iodide at 18 are quoted in Table XXXIII. At concentrations greater than 0.5 n,... [Pg.128]

The transference numbers of certain electrolytes, however, show variations from the predictions of the theory. The data for silver nitrate are plotted in Fig. 5 and it is seen that the variation of the transference number of that substance with concentration is in the opposite direction from that required by the theory. A somewhat similar behavior is observed with the data on potassium nitrate, the observed values changing much more rapidly with increasing concentration than would be expected from equation (28). However, as will be seen from a study of the conductance measurements, nitrates are somewhat abnormal. [Pg.334]

Lead code and CRC check code are automatically added by nRF905, wireless substation address code is 2 bytes which is the primary address location when distinguish the working area and the wind speed is abnormal Air-flow meter code is 4 bytes, and it is only corresponding to the number of the wind member, and it can ensure the source of the air monitoring data The superior relay station address code is used to control process that data transfers in wireless communication subnet. Air volume is defined as an integer that is 3 bytes, and the second byte is decimal point. [Pg.671]

The mechanism of the transfer of material across phase boundaries likew ise presents a number of novel and interesting problems. Here we have to consider firstly the abnormal... [Pg.471]

If the number of cations in abnormal sites is (mol cm 2) then the charge transferred to the cations from the metal will be X F z+F (C cm 2). It is convenient to define a quantity Q such that Q = q i A + where q is the charge remaining on the metal surface. The equivalent circuit for this situation is that of figure 6. At limiting low frequencies a double layer capacity will be found as... [Pg.265]


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