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Trans influence metal hydrides

The set of <5 molecular orbitals calculated for the complexes containing a bridging hydride is essentially similar to the orbital situation predicted for a diiridium(II) complex containing a metal-metal bond,[83] which is schematically shown also in Figure 3. From this Scheme, and taking into account the behavior of the hydrido bridged compounds, it seems very likely that trans influences and trans effects could also be transmitted from one metal to another in complexes containing metal-metal bonds, which constitute a very abundant class of complexes. [Pg.318]

The trans effect/influence in binuclear complexes brings about two main phenomena that are not observed in mononuclear complexes (i) the position of the bridging ligands is determined by the trans influences of ligands in both metals, and (ii) the trans effect/influence of a terminal ligand in one of the metal centers can be transmitted to the adjacent metal center via a bridging hydride or an intermetallic bond. [Pg.36]

See other pages where Trans influence metal hydrides is mentioned: [Pg.237]    [Pg.1101]    [Pg.1747]    [Pg.237]    [Pg.1101]    [Pg.1747]    [Pg.214]    [Pg.140]    [Pg.232]    [Pg.386]    [Pg.299]    [Pg.301]    [Pg.275]    [Pg.169]    [Pg.183]    [Pg.267]    [Pg.299]    [Pg.301]    [Pg.80]    [Pg.214]    [Pg.58]    [Pg.59]    [Pg.1569]    [Pg.182]    [Pg.214]    [Pg.32]    [Pg.59]    [Pg.97]    [Pg.317]    [Pg.5235]    [Pg.111]    [Pg.26]    [Pg.176]    [Pg.231]    [Pg.289]    [Pg.294]    [Pg.36]    [Pg.37]    [Pg.187]    [Pg.214]    [Pg.7]    [Pg.8]    [Pg.310]    [Pg.288]    [Pg.112]    [Pg.705]    [Pg.288]    [Pg.112]    [Pg.275]   
See also in sourсe #XX -- [ Pg.2 , Pg.705 ]



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