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Tosylmethyl isocyanide TosMIC , pyrrole synthesis

Isonitrile cyclization provides a useful alternative method of the Knorr type cyclization for pyrrole synthesis. In 1972, Leusen and coworkers reported pyrrole synthesis based on the reaction of tosylmethyl isocyanide (TosMIC) with electron-deficient alkenes (Eq. 10.12).15... [Pg.328]

Tosylmethyl isocyanide (TosMIC) was employed in a key step for the synthesis of bicyclic heterocycles from L-glutamic acid <01H(55)2099>, while benzyl isocyanoacetate was utilized for reaction with a-acetoxynitro compound 41 to yield the pyrrole 42, an intermediate in the synthesis of (+)-deoxypyrro oline, a putative cross-link of bone collagen <01JOC11>. [Pg.117]


See other pages where Tosylmethyl isocyanide TosMIC , pyrrole synthesis is mentioned: [Pg.115]    [Pg.378]    [Pg.126]    [Pg.111]    [Pg.120]    [Pg.142]    [Pg.327]    [Pg.142]   
See also in sourсe #XX -- [ Pg.328 , Pg.329 ]




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Isocyanides TosMIC

Isocyanides synthesis

Isocyanides, tosylmethyl

Pyrroles, synthesis

TosMIC

TosMIC isocyanide

Tosylmethyl isocyanide (TosMIC , pyrrole

Tosylmethyl isocyanide , pyrrole

Tosylmethyl isocyanide , pyrrole synthesis

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