Tolman

Tolman [21] concluded from thermodynamic considerations that with sufficiently curved surfaces, the value of the surface tension itsc//should be affected. In reviewing the subject, Melrose [22] gives the equation... 

The foregoing serves as an introduction to the detailed thermodynamics of the surface region the method is essentially that of Gibbs [35], as reviewed by Tolman [36, 37]. An additional relationship is... 

JR Tolman, JM Elanagan, MA Kennedy, JH Prestegard. Proc Natl Acad Sci USA 92 9279-9283, 1995. 

Tolman, V, Veres, K Collect Czech Chem Commun 1972,37,2962... 

Figure 2.74 Relationship between i/(C-0) for rrans-IrCl(CO)(PPhi)2 (in CHC13 solution) and Xi (Tolman s additivity substituent contribution for electronic effects in R3P). (See Chem.

The Pt—P (and Pt—Cl) bond lengths correlate with the electron-donating ability of the phosphine (Tolman s Xi factor) rather than steric factors (the cone angle of the tertiary phosphine) [150b]. 

R. C. Tolman, The Principle of Statistical Mechanics, pp. 146 ff., Oxford University Press, 1938. 

Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis. C. A. Tolman, Chem. Rev., 1977, 77, 313-348 (298). 

Tmta — see Acetic acid, trimethylenediaminetetra-Tollen s reagent, 5, 780 Tolman s cone angle, 2, 1015 Toluene acetoxylation... 

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