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10-TMS-9-BBD system

As can be inferred from the data presented in Table 1, the TMSCHN2 ring insertion process appeared to be a very general route to 10-TMS-9-BBD systems, the reactivity of 9-BBN-H dimer was examined as a potential... [Pg.474]

The 10-TMS-9-BBD system (1) is readily prepared frtmi many 9-BBN derivatives through the clean insertion of the stable, commercially available reagent, TMSC1B42. Resolution of the chiral bicyclic system is efficiently accomplished (40%) through its pseudoephedrine complex (8) vidiich is readily converted to the B-H (3), B-allyl (9) ot B-allenyl- 10-TMS-9-BBD(13) derivatives. These new reagents have been demonstrated to function as highly useful... [Pg.191]

See other pages where 10-TMS-9-BBD system is mentioned: [Pg.476]    [Pg.478]    [Pg.480]    [Pg.481]    [Pg.476]    [Pg.478]    [Pg.480]    [Pg.481]    [Pg.177]    [Pg.185]    [Pg.186]    [Pg.189]    [Pg.476]    [Pg.478]    [Pg.480]    [Pg.481]    [Pg.476]    [Pg.478]    [Pg.480]    [Pg.481]    [Pg.177]    [Pg.185]    [Pg.186]    [Pg.189]    [Pg.472]    [Pg.473]    [Pg.472]    [Pg.473]    [Pg.178]   
See also in sourсe #XX -- [ Pg.181 , Pg.182 , Pg.183 , Pg.184 , Pg.185 , Pg.186 , Pg.187 , Pg.188 , Pg.189 , Pg.190 ]



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