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Titanocenes Ti

Titanocene Ti-Chloro-Ti-pcntafluo-rophenyl- XIII/7. 305 (RjTiCl, + Ar-Li)... [Pg.715]

Titanocene, Ti-nicthyl Ti-pentafluo-rophenyl- Xlll/7. 303 (Ar — Li R,TiCI2)... [Pg.719]

Titanocen Ti-Dichloro-isopropyl-E18/1. 164 (Dienyl-Li + Dienyl-TiCI3)... [Pg.1151]

The appropriate incorporation of McsC or McsSi substituents has been found to lead to the solid open titanocenes, Ti[2,4-(Me3C)2C5H5]2 and Ti[l,5-(Me3Si)2 CsH5]2. The latter has been structurally characterized (Fig. 1) and found to adopt something close to the expected staggered conformation (5c). A conformation angle, x, of 82.5° was observed, defined relative to values of 0° and 180°, respectively, for the. syK-eclipsed and nnti-eclipsed conformations, 5a and 5b. [Pg.140]

Subsequently, another solid open titanocene, Ti(c-CgHii)2, was isolated.A structural study also revealed something close to a staggered conformation (X = 88.4°, Fig. 2), as expected. [Pg.140]

See other pages where Titanocenes Ti is mentioned: [Pg.112]    [Pg.155]    [Pg.674]    [Pg.729]    [Pg.729]    [Pg.730]    [Pg.32]    [Pg.3848]    [Pg.724]    [Pg.725]    [Pg.725]    [Pg.1023]    [Pg.1030]    [Pg.1041]    [Pg.1159]    [Pg.310]    [Pg.3847]    [Pg.203]    [Pg.555]    [Pg.455]    [Pg.141]    [Pg.206]   
See also in sourсe #XX -- [ Pg.2 , Pg.3 , Pg.4 , Pg.7 , Pg.141 , Pg.143 , Pg.144 ]



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Titanocene

Titanocenes

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