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Titanocene dichloride hydroalumination

Hydroalumination. Titanocene dichloride is an effective catalyst for hydro-uluminution of alkenes and alkynes with his(dialkylamino)alancs5 and various complex aluminum hydrides. The adducts can be quenched with water or iodine. The reaction is satisfactory for terminal alkenes and internal alkynes, but is not clcun for internal alkenes and terminal alkynes. [Pg.131]

The hydroalumination of terminal alkenes by LiAlH4 catalyzed by titanocene and zirconocene dichloride, CpjTiCh and CpjZrCh, respectively, has been reported by Isagawa [16] and Sato [14]. Again, the titartium compound proved to be more active... [Pg.49]

See other pages where Titanocene dichloride hydroalumination is mentioned: [Pg.751]   
See also in sourсe #XX -- [ Pg.751 ]

See also in sourсe #XX -- [ Pg.8 , Pg.751 ]

See also in sourсe #XX -- [ Pg.8 , Pg.751 ]



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Hydroalumination

Hydroaluminations

Titanocene

Titanocene dichloride

Titanocenes

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