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Titanium, dicyclopentadienyl derivatives

Transition metal carbodiimides, such as MnNCN and CuNCN, and carbodiimides derived from zinc, mercury,silver and thallium are also known. A preceramic polymeric titanium carbodiimide is obtained in the reaction of TiCU with bis(trimethyl-silyl)carbodiimide. Liganded carbodiimidotitanium complexes are obtained in the reaction of CpaTiCla with Me3SnN=C=NSi(i-Pr)3. ° Also, dicyclopentadienyl titanium (IV) diisocyanates are converted into carbodiimides with LiN(SrMe3)2. ... [Pg.214]

The previously isolated1654 / // -/rtitanium dichloride has been prepared by a new route, involving the reductive dimerization of 6-phenylfulvene with activated calcium powder followed by treatment with TiCl3/AlCl3 (1 3) and oxidation in air. This complex has been used to synthesize a variety of other // -derivatives through ligand replacement (Scheme 642). The reaction of 6,6-diphenylfulvene... [Pg.608]

See other pages where Titanium, dicyclopentadienyl derivatives is mentioned: [Pg.598]    [Pg.234]    [Pg.15]    [Pg.245]    [Pg.598]    [Pg.409]    [Pg.150]    [Pg.391]   


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Titanium dicyclopentadienyl

Titanium dicyclopentadienyls

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