Titanium complexes dicyclopentadienyl

Transition metal carbodiimides, such as MnNCN and CuNCN, and carbodiimides derived from zinc, mercury,silver and thallium are also known. A preceramic polymeric titanium carbodiimide is obtained in the reaction of TiCU with bis(trimethyl-silyl)carbodiimide. Liganded carbodiimidotitanium complexes are obtained in the reaction of CpaTiCla with Me3SnN=C=NSi(i-Pr)3. ° Also, dicyclopentadienyl titanium (IV) diisocyanates are converted into carbodiimides with LiN(SrMe3)2. ... 

The previously isolated1654 / // -/rtitanium dichloride has been prepared by a new route, involving the reductive dimerization of 6-phenylfulvene with activated calcium powder followed by treatment with TiCl3/AlCl3 (1 3) and oxidation in air. This complex has been used to synthesize a variety of other // -derivatives through ligand replacement (Scheme 642). The reaction of 6,6-diphenylfulvene... 

Cano, A. Cuenca, T. Gomez-Sal, R Manzanero, A. Royo, P. Dicyclopentadienyl titanium and zirconium complexes with the double bridged bis(dimethylsilanodiyl)dicyclopentadienyl [(Me2Si)2(ti -... 

Bis(7 --cyclopentadienyl)bis [bis(trifluoromethyl)phosphinoxy Jtitanium, (vr- 5116)2X1 OP(CFs)2 2, is obtained quantitatively from dicyclopentadienyl-titanium dichloride and (CF3)2P 0 P(CF3)2 at 85 °C in toluene in a sealed tube in contrast, titanium tetrachloride undergoes a complex reaction leading to unidentified products under the same conditions. 

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