Titanium complexes alkane elimination

Amidocarbonylation aldehydes, 11, 512 enamides, 11, 514 overview, 11, 511-555 Amido complexes with bis-Cp titanium, 4, 579 Group 4, surface chemistry on oxides, 12, 515 Group 5, surface chemistry on oxides, 12, 524 with molybdenum mono-Cp, 5, 556 with mono-Cp titanium(IV) alkane elimination, 4, 446 amine elimination, 4, 442 characteristics, 4, 413 via dehalosilylation reactions, 4, 448 HCL elimination, 4, 446 metathesis reactions, 4, 438 miscellaneous reactions, 4, 448 properties, 4, 437... 

The titanium-catalyzed addition of magnesium hydrides to alkanes was first reported by Ashby [22], but this reaction can be more conveniently carried out using alkyl-magnesium halides ( Bu, "Pr), because (3-hydride elimination from organotransition metal complexes to produce transition metal hydrides is generally very rapid (RCH2CH2MgX + M—X RCH.CH -M H—M + RCH- CH,). Thus, dimeriza-... 

The reaction of metal alkyl compounds with dihydrogen, leading to hydride species with elimination of alkanes, is commonly observed for Lewis acidic metal centers. This reaction has been used to prepare hydride complexes of the lanthanides, and of titanium(III), see equation 8 [39]. 

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